Extended chain crystal 構造
WebThis is the first paper of a series of reports concerning extended-chain crystals of flexible, linear high polymers. The general conditions for crystal growth are discussed. Polymer … WebNov 27, 2009 · The initial state for inducing lamellar crystal growth in a row structure is shown in Fig. 1, where the central fiber is formed by immobile extended chains, and the occupation density of bulk polymers, each containing 128 monomers, is 0.9375 in the amorphous matrix. To eliminate the effect of chain-end defects in the central fiber, we …
Extended chain crystal 構造
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WebThe kinetic theory of the rate of growth G and the initial lamellar thickness lg* of chain‐folded crystals is extended so that it is applicable at high undercoolings. Attention is centered on the details of how the first step element and the first fold are put down on the substrate. A parameter φ that varies between zero and unity, which apportions the free … WebJan 1, 1987 · Gel-spinning can produce high stiffness fibres from flexible polyethylene and semi-rigid polyethylene terephthalate, due to the extended-chains structure in the fibre. On the contrary, melt ...
WebPolylactide (PLA) forms an extended-chain crystal (ECC) in a Langmuir monolayer. Therefore, the chain packings in crystals can be identified by simply evaluating the crystal sizes. WebMar 1, 2001 · The connection between folded-chain and extended-chain crystals is demonstrated by the S-shaped extended-chain crystals as well as their direct morphological connection observed with SEM.
WebEXTENDED CHAIN CRYSTALS OF POLYMERS extended chain crystals is obvious. As soon as it has been established that no chain folds are present, this classification can be made. The crystal must in this case have at least the dimension of the helically fully extended molecule in the direction of the helix. FORMATION OF EXTENDED CHAIN … WebThe morphology of extended chain lamellae and fibrous polytetrafluoroethylene has been analyzed by electron microscopy and compared to polyethylene. The crystal growth …
WebFeb 13, 2024 · Polylactide (PLA) forms an extended-chain crystal (ECC) in a Langmuir monolayer. Therefore, the chain packings in crystals can …
WebJan 8, 2003 · Series of SAXS traces of extended-chain solution-grown crystals of alkane C 216 H 385 D 49 recorded during heating at 18C/min from 60 to 1308C. The intensities are Lorentz corrected. thunderbird will do just fine chordsWebSep 1, 2015 · The extended-chain crystal structure of the UHMWPE fibers prepared by melt spinning method was studied with WAXD, DSC and SEM. At draw ratio (DR) values higher than 24, double melting peaks were observed from the DSC thermograms, the corresponding temperatures being 137.1–142°C and 142–145°C, respectively. With the … thunderbird will not accept my passwordWebMay 1, 2024 · For example, a typical feature is that D-A conjugated polymers generally adopt an extended chain in crystals [71], which is significantly different from the folded chain conformation in flexible ... thunderbird where are emails storedWebStudies of extended chain crystals carried out over the last 10 years have been reviewed. Crystallization in an extended chain conformation is possible either by chain folding followed by extension in the solid state, or by crystallization during polymerization. The equilibrium isometric crystal habit is only rarely exhibited. Crystals which derive from … thunderbird wiki mythologyWebApr 7, 1997 · Crystallization and growth of an isolated extended chain single crystal (ECSC) of polyethylene (PE) under high pressure from the melt into the mobile phase, such as hexagonal phase, was studied by in-situ optical microscopy and transmission electron microscopy. Direct evidence is obtained that an isolated ECSC was formed from a folded … thunderbird wild west casinothunderbird wikipediaWebIsolation of extended-chain crystals from high-pressure crystallized polyethylene by selective dissolution. Abstract In recent years the formation of extended-chain crystals … thunderbird will not send emails